Visualizing excited state dynamics of conjugated molecules trough femtosecond stimulated Raman scattering
نویسندگان
چکیده
منابع مشابه
Femtosecond stimulated Raman study of excited-state evolution in bacteriorhodopsin.
Femtosecond time-resolved stimulated Raman spectroscopy (FSRS) is used to examine the photoisomerization dynamics in the excited state of bacteriorhodopsin. Near-IR stimulated emission is observed in the FSRS probe window that decays with a 400-600-fs time constant. Additionally, dispersive vibrational lines appear at the locations of the ground-state vibrational frequencies and decay with a 26...
متن کاملFemtosecond excited-state dynamics of a conjugated ladder polymer.
Aniong the known classes of nonlinear optical materials, z-conjugated polymers are very attractive because of their large, third-order optical susceptibilities and ultrafast response times.lP5 The large optical nonlinearity of conjugated polymers has long been recognized as arising from the z-electron delocalization along the polynler chains2 Recently, aromatic heterocyclic ladder-type polymers...
متن کاملFemtosecond time-resolved Raman spectroscopy using stimulated Raman scattering
Femtosecond Raman spectroscopy has been developed to investigate ultrafast photoinduced structural changes of materials. Vibrational modes in the photogenerated transient species are measured by stimulated Raman scattering using a Raman pump pulse with narrow bandwidth and a femtosecond supercontinuum probe pulse. The Raman signal can be measured without slowing the temporal response and broade...
متن کاملAnalysis of femtosecond stimulated Raman spectroscopy of excited-state evolution in bacteriorhodopsin.
The dispersive lines observed in time-resolved femtosecond stimulated Raman spectroscopy (FSRS), using a pair of 809 nm, 3 ps Raman pump, and 840-960 nm ultrashort probe pulse, for the first 500 fs photoisomerization dynamics in the excited state of bacteriorhodopsin, BR* (S(1)), created by a prior 500 nm, 35 fs actinic pump pulse, have previously been attributed to Raman initiated by nonlinear...
متن کاملExcited-State Proton Transfer of Photoexcited Pyranine in Water Observed by Femtosecond Stimulated Raman Spectroscopy
We use femtosecond stimulated Raman spectroscopy (FSRS) to illuminate the choreography of intermolecular excited-state proton transfer (ESPT) of photoacid pyranine (8-hydroxypyrene-1,3,6-trisulfonic acid, HPTS) in water. The multidimensional reaction coordinate responsible for photoacidity is revealed to involve sequential activation of characteristic skeletal motions during the ca. 1 ps prepar...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: EPJ Web of Conferences
سال: 2019
ISSN: 2100-014X
DOI: 10.1051/epjconf/201920509015